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71.
Sang Kyu Lee Min Ju Cho Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):531-542
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007 相似文献
72.
Pál Sohár Gábor Bernáth Géza Stájer Angela E. Szabo 《Magnetic resonance in chemistry : MRC》1989,27(9):872-876
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments. 相似文献
73.
Wei-Yan Shao Ying-Nan Cao Wen-Jie Pan Xian-Zhang Bu Lin-Kun An Lian-Quan Gu Albert S.C. Chan 《Tetrahedron letters》2006,47(24):4085-4089
Seventeen unsymmetrical curcumin derivatives were synthesized in good yield and purity by a facile solid phase synthesis strategy. 相似文献
74.
75.
合成了两种新型噻吩基卟啉-5,15-二(2-噻吩基)-2,8,12,18-四乙基-3,7,13,17-四甲基卟啉7a(45.1%)和5,15-二(2-联噻吩基)-2,8,12,18-四乙基-3,7,13,17-四甲基卟啉7b(61.2%),并研究了它们的光谱性质,其中荧光光谱的最大发射峰蜂都在631nm处,量子产率分别为4.1%(7a)和1.4%(7b)。 相似文献
76.
77.
Eremenko L. T. Oreshko G. V. Nesterenko D. A. Lagodzinskaya G. V. Eremenko I. L. 《Russian Chemical Bulletin》2002,51(1):157-159
The reactions of ethylene glycol mononitrate and glycerol 1,3-dinitrate with methylphosphonic dichloride afforded new nitroxyalkyl methylphosphonates. 相似文献
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79.
80.
Dendritic nanocrystalline CdS film was deposited at liquid-liquid interface of surfactants and an electrolyte containing 4 mmol L−1 cadmium chloride (CdCl2) and 16 mmol L−1 thioacetamide (CH3CSNH2) with an initial pH value of 5 at 15 °C by electrochemical synthesis. The nanofilm was characterized by transmission electron microscopy (TEM), field emission scanning electron microscope (FE-SEM), atomic force microscopy (AFM), ultraviolet visible (UV-vis) absorption spectroscopy and fluorescence spectroscopy. The surface morphology and particle size of the nanofilm were investigated by AFM, SEM and TEM, and the crystalline size was 30-50 nm. The thickness of the nanofilm calculated by optical absorption spectrum was 80 nm. The microstructure and composition of the nanofilm was investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), showing its polycrystalline structure consisting of CdS and Cd. Optical properties of the nanofilm were investigated systematically by UV-vis absorption and fluorescence spectroscopy. A λonset blue shift compared with bulk CdS was observed in the absorption spectra. Fluorescence spectra of the nanofilm indicated that the CdS nanofilm emitted blue and green light. The nanocomposites film electrode will bring about anodic photocurrent during illumination, showing that the transfer of cavities produces photocurrent. 相似文献